Caesium-137
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For the band, see Cesium 137 (band).
| Caesium-137 | |
|---|---|
| General | |
| Name, symbol | Caesium-137,137Cs |
| Neutrons | 82 |
| Protons | 55 |
| Nuclide data | |
| Natural abundance | 0 (artificial element) |
| Half-life | 30.17 y[1] ± 0.03 y |
| Parent isotopes | 137Xe (β−) |
| Decay products | 137mBa |
| Isotope mass | 136.907 u |
| Spin | 11⁄2− |
| Decay mode | Decay energy |
| beta, gamma | 1.176 [2] MeV |
| Thermal | Fast | 14 MeV | |
|---|---|---|---|
| 232Th | not fissile | 6.30 ± 0.30 | 6.29 ± 0.99 |
| 233U | 6.21 ± 0.22 | 6.51 ± 0.31 | 5.06 ± 0.43 |
| 235U | 6.221 ± 0.069 | 5.889 ± 0.096 | 5.6 ± 1.3 |
| 238U | not fissile | 6.02 ± 0.15 | 5.62 ± 0.68 |
| 239Pu | 6.594 ± 0.080 | 6.36 ± 0.12 | ? |
| 241Pu | 6.28 ± 0.14 | 6.37 ± 0.18 | ? |
Radio-cesium, Caesium-137 (137
55Cs, Cs-137), or cesium-137, is a radioactive isotope ofcaesium which is formed as a fission product by nuclear fission.
55Cs, Cs-137), or cesium-137, is a radioactive isotope ofcaesium which is formed as a fission product by nuclear fission.
[edit]Decay
It has a half-life of about 30.17 years,[1] and decays by beta emission to a metastablenuclear isomer of barium-137: barium-137m (137mBa, Ba-137m). (About 95 percent of the nuclear decay leads to this isomer. The other 5.0 percent directly populates the ground state, which is stable.) Ba-137m has a half-life of about 153 seconds, and it is responsible for all of the emissions of gamma rays. One gram of caesium-137 has anactivity of 3.215 terabecquerel (TBq).[4]
The photon energy of Ba-137m is 662 keV. These photons can be useful infood irradiation and in the radiotherapyof cancer. Caesium-137 is not widely-used for industrial radiography because it is quite chemically reactive, and hence, difficult to handle. Also the salts of caesium are very soluble in water, and this complicates the safe handling of caesium. Cobalt-60, 60
27Co, is preferred for radiography, since it is chemically a rather nonreactive metal offering higher energy gamma-ray photons. Caesium-137 can be found in some moisture and density gauges, flow meters, and related sensors.
27Co, is preferred for radiography, since it is chemically a rather nonreactive metal offering higher energy gamma-ray photons. Caesium-137 can be found in some moisture and density gauges, flow meters, and related sensors.
[edit]Uses
Caesium-137 has a small number of practical uses. In small amounts, it is used to calibrate radiation-detection equipment. It is used as a gamma emitter for oilfield wireline density measurements. It is also sometimes used in cancer treatment, and it is also used industrially in gauges for measuring liquid flows and the thickness of materials.[5]
[edit]Radioactive caesium in the environment
Small amounts of caesium-134 and caesium-137 were released into the environment during nearly allnuclear weapon tests and some nuclear accidents, most notably the Chernobyl disaster. As of 2005, caesium-137 is the principal source of radiation in the zone of alienation around the Chernobyl nuclear power plant. Together with caesium-134, iodine-131, and strontium-90, caesium-137 was among the isotopes, distributed by the reactor explosion, which constitute the greatest risk to health.
As of April 2011, it was also being found after theFukushima Daiichi nuclear disasters in Japan. In July 2011, meat from 11 cows shipped to Tokyo from Fukushima prefecture was found to have 1,530 to 3,200 Bq/kg of Cs-137, considerably exceeding the Japanese legal limit of 500 becquerels.[6] In Scandinavia, some reindeer and sheep exceeded the Norwegian legal limit (3000 Bq/kg), 26 years after Chernobyl.[7]
The mean contamination of caesium-137 in Germany following the Chernobyl disaster was 2000 to 4000 Bq/m2. This corresponds to a contamination of 1 mg/km2 of caesium-137, totaling about 500 grams deposited over all of Germany.[citation needed]
Caesium-137 in the environment is anthropogenic (man-made). Unlike most other radioisotopes, caesium-137 is not produced from its non-radioactive isotope but as a byproduct of nuclear fission,[8] meaning that until now, it has not occurred on Earth for billions of years. By observing the characteristic gamma rays emitted by this isotope, it is possible to determine whether the contents of a given sealed container were made before or after the advent of atomic bomb explosions. This procedure has been used by researchers to check the authenticity of certain rare wines, most notably the purported "Jefferson bottles". [9] It is also possible to date soils and sediments, given the short life of Cs137 across the Earth's entire surface.
[edit]Health risk of radioactive caesium
| Actinides | Half-life | Fission products | ||||||
|---|---|---|---|---|---|---|---|---|
| 244Cm | 241Pu f | 250Cf | 243Cmf | 10–30 y | 137Cs | 90Sr | 85Kr | |
| 232U f | 238Pu | f is for fissile | 69–90 y | 151Sm nc➔ | ||||
| 4n | 249Cf f | 242Amf | 141–351 y | No fission product has half-life 102 to 2×105 years | ||||
| 241Am | 251Cf f | 431–898 y | ||||||
| 240Pu | 229Th | 246Cm | 243Am | 5–7 ky | ||||
| 4n | 245Cmf | 250Cm | 239Pu f | 8–24 ky | ||||
| 233U f | 230Th | 231Pa | 32–160 ky | |||||
| 4n+1 | 234U | 4n+3 | 211–290 ky | 99Tc | 126Sn | 79Se | ||
| 248Cm | 242Pu | 340–373 ky | Long-lived fission products | |||||
| 237Np | 4n+2 | 1–2 My | 93Zr | 135Cs nc➔ | ||||
| 236U | 4n+1 | 247Cmf | 6–23 My | 107Pd | 129I | |||
| 244Pu | 80 My | >7% | >5% | >1% | >.1% | |||
| 232Th | 238U | 235U f | 0.7–12 Gy | fission product yield | ||||
Caesium-137 reacts with water producing a water-soluble compound (caesium hydroxide), and the biological behavior of caesium is similar to that of potassium and rubidium. After entering the body, caesium gets more or less uniformly distributed throughout the body, with higher concentration in muscle tissues and lower in bones. The biological half-life of caesium is rather short at about 70 days.[10] Experiments with dogs showed that a single dose of 3800 μCi/kg (140 MBq/kg, or approximately 44 μg/kg) is lethal within three weeks.[11]
Accidental ingestion of caesium-137 can be treated with Prussian blue, which binds to it chemically and reduces the biological half-life to 30 days.[12]
[edit]Incidents
The improper handling of caesium-137 gamma ray sources can lead to release of this radioisotope and radiation injuries. Perhaps the best-known case is the Goiânia accident of 1985, in which an improperly-disposed-of radiation therapy system from an abandoned clinic in the city of Goiânia, Brazil, was scavenged from a junkyard, and the glowing caesium salt sold to curious, uneducated buyers. This led to four deaths and serious injuries from radiation exposure.[13]
Caesium gamma-ray sources that have been encased in metallic housings can be mixed-in with scrap metal on its way to smelters, resulting in production of steel contaminated with radioactivity.[14]
One notable example was the Acerinox accident of 1998, when the Spanish recycling company Acerinox accidentally melted down a mass of radioactive caesium-137 that came from a gamma-ray generator.[15]
In 2009, a Chinese cement company (in Tongchuan, Shaanxi Province) was demolishing an old, unused cement plant and did not follow standards for handling radioactive materials. This caused some caesium-137 from a measuring instrument to be included with eight truckloads of scrap metal on its way to a steel mill, where the radioactive caesium was melted down into the steel.[16]
[edit]See also
| Prop: Unit: | t½ a | Yield % | Q * keV | βγ * |
|---|---|---|---|---|
| 155Eu | 4.76 | .0803 | 252 | βγ |
| 85Kr | 10.76 | .2180 | 687 | βγ |
| 113mCd | 14.1 | .0008 | 316 | β |
| 90Sr | 28.9 | 4.505 | 2826 | β |
| 137Cs | 30.23 | 6.337 | 1176 | βγ |
| 121mSn | 43.9 | .00005 | 390 | βγ |
| 151Sm | 90 | .5314 | 77 | β |
[edit]References
- ^ a b National Institute of Standards and Technology. "Radionuclide Half-Life Measurements". Retrieved 2011-11-07.
- ^ The Lund/LBNL Nuclear Data Search. "Nuclide Table". Retrieved 2009-03-14.
- ^ http://www-nds.iaea.org/sgnucdat/c1.htm Chain Fission Yields, IAEA
- ^ "NIST Nuclide Half-Life Measurements". NIST. Retrieved 13 March 2011.
- ^ http://www.bt.cdc.gov/radiation/isotopes/cesium.asp
- ^ "High levels of caesium in Fukushima beef". Independent Online. 9 July 2011.
- ^ Michael Sandelson; Lyndsey Smith (21st May, 2012). "Higher radiation in Jotunheimen than first believed". The Foreigner. Retrieved 2012-05-21.
- ^ Takeshi Okumura (October 21, 2003). "The material flow of radioactive cesium-137 in the U.S. 2000". http://www.epa.gov/. US Environmental Protection Agency.
- ^ http://www.winespectator.com/webfeature/show/id/42436
- ^ R. Nave. "Biological Half-life". Hyperphysics.
- ^ H.C. Redman et al. (1972). "Toxicity of 137-CsCl in the Beagle. Early Biological Effects". Radiation Research 50 (3): 629–648.DOI:10.2307/3573559. JSTOR 3573559. PMID 5030090.
- ^ http://www.bt.cdc.gov/radiation/prussianblue.asp
- ^ The Radiological Accident in Goiânia. IAEA. 1988.
- ^ "Radioactive Scrap Metal". NuclearPolicy.com. Nuclear Free Local Authorities. October 2000.
- ^ J.M. LaForge (1999). "Radioactive Caesium Spill Cooks Europe". Earth Island Journal (Earth Island Institute) 14 (1).
- ^ "Chinese 'find' radioactive ball". BBC News. 27 March 2009.
